publication
Journal Article
2010
Switching from (R)- to (S)-selective chemoenzymatic DKR of amines involving sulfanyl radical-mediated racemization
ElBlidi, Lahssen . 2010
Chemoenzymatic dynamic kinetic resolution (DKR) of amines involving sulfanyl radical-induced racemization happened to be the very first switchable DKR process allowing the synthesis of either (R)- or (S)-amides, in good yield and high enantiomeric excess, depending on the nature of the enzyme; the different steps of the development of (S)-selective DKR are discussed.
Volume Number
8
Issue Number
18
Magazine \ Newspaper
Organic & Biomolecular Chemistry
Pages
4165-4168
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