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Dr Ammar TIGHEZZA

Associate Professor

Faculty

كلية العلوم
2 A 146 Building 5
publication
Journal Article
2022

Facile synthesis of hierarchical ZnS@ FeSe2 nanostructures as new energy-efficient cathode material for advanced asymmetric supercapacitors

Graphical abstract

 

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Abstract

We have effectively synthesized ZnS, FeSe2, and their nanocomposite in this study using a straightforward and affordable solvothermal process. We also investigate for the first time their ideal electrochemical performance for supercapacitors. The ZnS and FeSe2 positive electrodes exhibit capacitances of 266.2 F g-1 and 294.3 F g-1, respectively, with fascinating nanostructures and morphology. Their respective nanocomposites, AZ-1, AZ-2, and AZ-3, deliver capacitances of 356.8, 444.4, and 326.1 F g-1 with significant rate performance in aqueous solution in three-electrode assembly. The lowest ESR and Rct values of AZ-2 electrodes, which improved conductivity and charge transport kinetics and created a synergistic effect between ZnS and FeSe2 electrodes, are responsible for their exceptional capacitative performance. We built an asymmetric supercapacitor (AZ-2/AC) with an optimal voltage of 1.6 V, which demonstrated great power density (6250 W kg-1) and energy density (33 Wh kg-1) with remarkable cycling stability (88.1%) in an aqueous electrolyte after 12,000 cycles. As a result, FeSe2-based nanocomposites are strong contenders for realizing high energy and power delivery for practical applications.

Publication Work Type
Research
Publisher Name
ScienceDIrect
Magazine \ Newspaper
Journal of Science: Advanced Materials and Devices
more of publication
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by Malak Azmat Ali, M. Musa Saad H.‑E., Ammar M. Tighezza, Shaukat Khattak, Samah Al‑Qaisi, Muhammad Faizan
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The research was done on the creation and use of bi-metal sulfide thin film, Nd2S3:Ni9S8. 41 nm-sized crystallites with 80% crystallinity were found in the material. The evaluated optical…

by Mahwash Mahar Gul, Khuram Shahzad Ahmad, Andrew Guy Thomas, Ammar Mohamed Tighezza
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Perovskite solar cell (PSC) technology is extensively used in commercial sectors, but concerns about the use of lead and degradable components in cells are increasing.

by Farhana Bari Sumona, Muhammad Kashif, Eli Danladi, Ammar M. Tighezza, Nahid Al-Mahmud, Gazi F. I. Toki, Rahul Pandey, and M. Khalid Hossain
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