A new Initiating System Based on[(SiMes)Ru(PPh3)(Ind)Cl2] Combined with Azobisisobutyronitrile in the Polymerization and Copolymerization of Styrene and Methylmethacrylate
NOLAN, ABDULLAH M. AL-MAJID WASEEM SHARAF SHAMSAN , ABDELBASIT M. ALODAYN, TAIEB AOUAK*, and STEVEN P. . 2017
The homopolymerization and copolymerization of styrene and methyl methacrylate, initiated for the first time by the combination of azo-bis-isobutyronitrile (AIBN) with [(SiMes)Ru(PPh3)(Ind)Cl2] complex. The reactions were successfully carried out, on a large scale, in presence this complex at 80 °C. It was concluded from the data obtained that the association of AIBN with the ruthenium complex reduces considerably the transfer reactions and leads to the controlled radical polymerization and the well-defined polymers.
Volume Number
20
Issue Number
1
Magazine \ Newspaper
DESIGNED MONOMERS AND POLYMERS
Pages
167 to 176
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