Discrete Supramolecular Stacks Based on Multinuclear Tweezer- Type Rhodium Complexes
: By taking advantage of self-complementary p–p stacking and CH–p interactions, a series of discrete quadruple stacks were constructed through the self-aggregation of U-shaped dirhodium metallotweezer complexes featuring various planar polyaromatic ligands. By altering the conjugate stacking strength and bridging ligands, assemblies with a range of topologies were obtained, including a binuclear D-shaped macrocycle, tetranuclear open-ended cagelike frameworks, and duplex metallotweezer stacking structures.