Infrared spectroscopy of Ca (NH3)n complexes.
Infrared spectra of Ca(NH3)n complexes in the gas phase have been recorded for the first time. The spectra are consistent with structures where the Ca atom resides inside one or more solvation shells of NH3 molecules. IR spectra were recorded using a photodissociation technique. A comparison of the spectra with those predicted from ab initio calculations suggests that Ca(NH3)8 has all NH3 molecules in a single solvent shell around the Ca atom, whereas the spectra of Ca(NH3)9 and Ca(NH3)10 are consistent with two-shell structures.
The continuous development of microelectronics requires mechanically enhanced insulating materials with a lower dielectric (low-k) constant. To accomplish this, in this paper, low-k polymer…
Here, we have manufactured extremely porous photoelectrodes comprised of ZnO/TiO2 by adding lignocellulose (LC) fibers extracted from the self-growing plant (Lily) on fluorine-doped tin oxide (FTO…
Present research work focuses on the synthesis of novel azo-dye Cu(II), Ni(II) and Co(II) chelates of Schiff base based ligand having antimicrobial activities. Azo-dye Cu(II) and Zn(II) complexes…